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A Sunscreen Ingredient To Avoid

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Saturday, April 17, 2010

A Sunscreen Ingredient To Avoid

It's kind of weird that I didn't blog about this earlier. I definitley knew about this controversy, but I didn't form a final verdict on it because of the conflicting studies. Being an advocate for safe skin lightening, I think it's always better to be safe than sorry, so I am going to roll with what many other skin care gurus are recommending and that is to avoid the sunscreen ingredient, oxybenzone.

We've all seen this ingredient before in numerous sunscreens. It's been around for decades. Particularily in US brand sunscreens, which 90% of the time feature this chemical filter. The problem with oxybenzone (also known as Benzophenone-3) is that, during the last decade or so, many dermatologists have criticized and re-evaluated the safety of this sunscreen ingredient. The original studies released to the public proving its safety were done in the 70s!

It all began with people complaining about excess (and I emphasize excess, like extreme) irritation and flushing from using sunscreens that had oxybenzone. Now, a lot of chemical filters can potentially irritate the skin, but oxybenzone is a different case. Studies have shown that oxybenzone can trigger allergies in people, be toxic to cells, and act as an endochrine disruptor (hormonal imbalance).

What is worse is that oxybenzone is very easily absorbed in the bloodstream. Most sunscreen ingredients get absorbed as well (but not as rapidly or in such significant amounts as oxybenzone), but oxybenzone has dangerous elements to it (which other filters do not have).

It can definitley hinder the process of skin lightening. Studies show that oxybenzone contributes to cell damage. This is done through free radical attraction. The forming of free radicals not only age the skin and damage the entire function of the skin, but many times can trigger excess melanin production and contribute to oxidation (the 'dull' or 'dark' look that comes as the day progresses).

There is also the issue of oxybenzone being a an endochrine disruptor. Never mind the fact that disrupting the balance of hormones has extreme effects on the body as a whole, but can be particularily bad for melasma sufferers. A large percentage of people who have melasma have some hormonal imbalance (through pregnancy, medication, age). Using oxybenzone can definitley worsen melasma patches and discolorations.

I should also emphasize that pregnant women should avoid oxybenzone just as much as they should avoid an rx retinoid (vitamin A) and hydroquinone. There have reports proving that women who used oxybenzone based sunscreens throughout their pregnancy gave birth to babies with abnormalities and low birth weight. There are some studies that dispell this claim, stating that 'normal' amounts of oxybenzone (such as, using an oxybenzone based sunscreen just on your face and neck, not your whole body) cannot cause any harm to a pregnant woman or her child. But, personally I would avoid it.

Now, you're probably wondering why companies put oxybenzone in their sunscreens anyway. Well, there are many reasons. The most obvious being that the FDA did approved it back in the 70s as a safe sunscreen ingredient. Also, it is a good sunscreen ingredient in the sense that it can help stabilize avobenzone (to a degree) and allow for better absorption (or forming of the protective coating) of other chemicals.

This is very similar to the whole unstable sunscreen issue. Many sunscreens that have unstable ingredients are bad for your skin. They break down when exposed to the sun, accelerate the aging process, and contribute to free radical damage. That is why it is important to look for certain sunscreen ingredient combinations. I outlined them in Sunscreen Etiquette.

Generally avobenzone is the culprit (which is why I avoid it). Oxybenzone is usually also coupled with avobenzone. Octinoxate should never be in a sunscreen that has avobenzone. Also never use titanium dioxide or zinc oxide with an avobenzone based sunscreen (unfortunatley a lot of foundations/powders have these uncoated minerals so makeup with a sunscreen with avobenzone is not a good idea).

Here are two links outlining the oxybenzone controversy:

CDC: Americans Carry Body Burden of Toxic Sunscreen Chemical

Concentrations of the Sunscreen Agent Benzophenone-3 in Residents of the United States: National Health and Nutrition Examination Survey 2003–2004

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11 Comments:

Anonymous Anonymous said...

hey mileena, i read on one of your posts that you may be able to help find the % of an ingredient in a product? well, i tried finding it out myself, but to no avail. i even called the company, but they responded that they didn't have that information.. maybe you can help?

the product:
olay quench body lotion - advanced healing
(fragrance free, with vitamin e + vita-niacin)

the ingredient i'm interested in:
niacinamide

listed ingredients:
WATER, GLYCERIN, NIACINAMIDE, PETROLATUM, ISOPROPYL ISOSTEARATE, CAPRYLIC/CAPRIC TRIGLYCERIDE, TOCOPHERYL ACETATE, DIMETHICONE, STEARYL ALCOHOL, CETYL ALCOHOL, PANTHENOL, ALUMINUM STARCH OCTENYLSUCCINATE, POLYETHYLENE, SODIUM ACRYLATES COPOLYMER, BEHENYL ALCOHOL, BENZYL ALCOHOL, CETEARYL ALCOHOL, CETEARYL GLUCOSIDE, DIMETHICONOL, DISODIUM EDT, STEARIC ACID, PEG-100 STEARATE, ETHYLPARABEN, METHYLPARABEN, PROPYLPARABEN, LAURETH-7, SODIUM HYDROXIDE, TITANIUM DIOXIDE.

so as you can see, niacinamide is the 3rd ingredient, after water and glycerin, so i guess there's a reasonable amount, but as you've stated, the % is key... :)

April 18, 2010 at 2:23 PM  
Blogger Mileena said...

Hi!

Yeah you're right that the higher the ingredient is listed, the more concentrated it is. I've read somewhere that the Olay Regenerist Serum has 3% niacinamide. I believe it is also the 3rd or maybe 4th ingredient on the list.

Usually e-mailing them for the information gets you the exact amount. That's strange they couldn't provide you that.

But I'm guessing since the serum ('serum' being a concentrated product) is 3%, the Olay Quench is probably 3% as well. Generally 5% is needed for skin lightening and acne reduction. You can also mix niacinamide (from bulkactives and other sites that carry it) into a niacinamide based serum or search the web for DIY niacinamide toners. I've been hearing a lot about them recently and the net is filled with useful information regarding making a 5% miture.

=)

April 18, 2010 at 2:36 PM  
Anonymous Anonymous said...

Hi Mileena,

This post is extremely helpful. The difficulty is finding sunscreens that don't have avobenzone and titanium dioxide together. Even the Vichy Ultra Fast Drying Fluid SPF 20 has both avobenzone (Parsol 1789) and titanium dioxide. Do you have any recommendations? Thanks!

April 18, 2010 at 3:38 PM  
Blogger Mileena said...

Hi! Yeah, I know even with the Vichy Fast Drying Fluid it contains uncoated minerals with the avobenzone. The mexoryl fortunatley kind of counteracts that problem because it is strong enough on its own to protect against UVA/UVB rays.

There are a lot of great sunscreens out there. I might do a post just listing my favs. But depending on your skin type here is a couple I have tried and liked:

sensitive skin types = Devita SPF 30

oily/acne prone skin types = Sofina UV Lucent (the best ever! I love this sunscreen. It is so matte and lightweight. I do use a cleansing oil to remove it though because it is so matte).

normal-dry skin types = Aveeno Ultra Calming SPF 30 (really gentle. great one)

combination = Elta MD SPF 46 (semi-matte, very nice finish).

=)

April 18, 2010 at 5:03 PM  
Anonymous Anonymous said...

...was researching the effects of niacineamide and found your blog...some good info. As far as the sunscreen brand recommendations above, I agree with Devita. However Sofina is pure junk. Below is the list of ingredients it contains. Pay special attention to ETHYLHEXYL METHOXYCINNAMATE (similar and as bad a avobenzone/oxybenzone etc, DIMETHICONE,TITANIUM DIOXIDE (titanium is a heavy metal and if not coated properly enters the blood/tissue and never leaves).
I suggest Australian brand Soleo and US brand BurnOut. As for face, Devita is one of the most decent options.
ZINC OXIDE
ETHYLHEXYL METHOXYCINNAMATE
DIMETHICONE
WATER
CYCLOMETHICONE
ALCOHOL
LAURYL METHACRYLATE/GLYCOL DIMETHACRYLATE CROSSPOLYMER
TALC
PERFLUOROHEXYLETHYL DIMETHYLBUTYL ETHER
GLYCERIN
PEG-12 DIMETHICONE
TITANIUM DIOXIDE
EUCALYPTUS GLOBULUS LEAF EXTRACT
THUJOPSIS DOLABRATA EXTRACT
CETY-PG HYDROXYETHYL PALMITAMIDE
BIS-METHOXYPROPYLAMIDO ISODOCOSANE
BUTYLENE GLYCOL
CERAMIDE 2
HYDROXYETHYL ISOSTEARYLOXY ISOPROPANOLAMINE
HYDROXYUNDECANOIC ACID
POLYSILICONE-9
METHICONE
ALUMINA
SILICA
BHT

April 18, 2010 at 7:32 PM  
Blogger Mileena said...

Thanks for the rec! I've never heard of Soleo or Burnout. ;)

April 19, 2010 at 11:14 AM  
Anonymous Anonymous said...

Hi Mileena,

Does octinoxate act like oxybenzone. Is this ingrident can be harmful for melasma sufferer or no . I heard that this can be toxix to skin cell as well is this right or no. I am currentyly using obagi healty skin ingridents are Octinoxate 7.5%, Zinc Oxide 9% . Pls help!!!

April 19, 2010 at 11:40 AM  
Blogger Mileena said...

No, not at all. Octinoxate is definitley not harmful to cells like oxybenzone.

Octinoxate and avobenzone however TOGETHER should not be used since they destabilize one anohter.

Zinc Oxide and Octinoxate is perfectly fine. That is a good combination, actually. Many sunscreens contain this and it is stable and not harmful at all to melasma or surrounding skin.

=)

April 19, 2010 at 3:32 PM  
Anonymous Randy said...

i see i see... no i cant see haha!!!

April 24, 2010 at 5:17 AM  
Blogger Jennifer said...

What about Oxybenzone USP 6.0%?

July 19, 2010 at 9:53 AM  
Blogger Mileena said...

Same thing. OXybenzone USP 6.0 poses endochrine disruptor/free radical damage properties.

July 19, 2010 at 10:49 AM  

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